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Abstract The chemical and isotopic characteristics of a solidified pluton represent the integration of magmatic and sub-solidus processes operating across a range of spatial and temporal scales during pluton construction, crystallization, and cooling. Disentangling these processes and understanding where chemical and isotopic signatures were acquired requires the combination of multiple tools tracing processes at different time and length scales. We combine whole-rock oxygen and Sr-Nd isotopes, zircon oxygen isotopes and trace elements, and mineral compositions with published high-precision U-Pb zircon geochronology to evaluate differentiation within the bimodal Guadalupe Igneous Complex, Sierra Nevada, California (USA). The complex was constructed in ~300 k.y. between 149 and 150 Ma. Felsic magmas crystallized as centimeter- to meter-sized segregations in gabbros in the lower part of the complex and as granites and granophyres structurally above the gabbros. A central mingling zone separates the mafic and felsic units. Pluton-wide δ18O(whole-rock), δ18O(zircon), and Sr-Nd isotopic ranges are too large to be explained by in situ, closed-system differentiation, instead requiring open-system behavior at all scales. Low δ18O(whole-rock) and δ18O(zircon) values indicate assimilation of hydrothermally altered marine host rocks during ascent and/or emplacement. In situ differentiation processes operated on a smaller scale (meters to tens of meters) for at least ~200 k.y. via (1) percolation and segregation of chemically and isotopically diverse silicic interstitial melt from a heterogeneous gabbro mush; (2) crystal accumulation; and (3) sub-solidus, high-temperature, hydrothermal alteration at the shallow roof of the complex to modify the chemical and isotopic characteristics. Whole-rock and mineral chemistry in combination with geochronology allows deciphering open-system differentiation processes at the outcrop to pluton scale from magmatic to sub-solidus temperatures over time scales of hundreds of thousands to millions of years. 

Abstract The Great Unconformity has been recognized for more than a century, but only recently have its origins become a subject of debate. Hypotheses suggest global Snowball Earth glaciations and tectonic processes associated with the supercontinent Rodinia as drivers of widespread kilometer-scale erosion in the late Neoproterozoic. We present new integrated zircon and apatite (U-Th)/He and fission-track thermochronology from Precambrian basement samples of the central Canadian Shield in northern Manitoba to test these ideas. Bayesian inverse modeling indicates that 150–200 °C of cooling (>3 km of exhumation) occurred simultaneously with Cryogenian glaciations at ca. 690–650 Ma within interior North America. This estimate for the timing of unroofing is more precise than previous appraisals and does not align with any known tectonic or magmatic events (i.e., large igneous province eruptions) potentially associated with the supercontinent cycle that occurred during the late Proterozoic along the Laurentian margins. Based on these results and interpretations, the timing and magnitude of exhumation is best explained by glacial erosion, and further establishes the importance of multiple thermochronometers for resolving detailed deeptime thermal histories. 

Refinements of the geological timescale driven by the increasing precision and accuracy of radiometric dating have revealed an apparent correlation between large igneous provinces (LIPs) and intervals of Phanerozoic faunal turnover that has been much discussed at a qualitative level. However, the extent to which such correlations are likely to occur by chance has yet to be quantitatively tested, and other kill mechanisms have been suggested for many mass extinctions. Here, we show that the degree of temporal correlation between continental LIPs and faunal turnover in the Phanerozoic is unlikely to occur by chance, suggesting a causal relationship linking extinctions and continental flood basalts. The relationship is stronger for LIPs with higher estimated eruptive rates and for stage boundaries with higher extinction magnitudes. This suggests LIP magma degassing as a primary kill mechanism for mass extinctions and other intervals of faunal turnover, which may be related to CO 2 ,   SO 2 , Cl, and F release. Our results suggest continental LIPs as a major, direct driver of extinctions throughout the Phanerozoic. 

The origin of the phenomenon known as the Great Unconformity has been a fundamental yet unresolved problem in the geosciences for over a century. Recent hypotheses advocate either global continental exhumation averaging 3 to 5 km during Cryogenian (717 to 635 Ma) snowball Earth glaciations or, alternatively, diachronous episodic exhumation throughout the Neoproterozoic (1,000 to 540 Ma) due to plate tectonic reorganization from supercontinent assembly and breakup. To test these hypotheses, the temporal patterns of Neoproterozoic thermal histories were evaluated for four North American locations using previously published medium- to low-temperature thermochronology and geologic information. We present inverse time–temperature simulations within a Bayesian modeling framework that record a consistent signal of relatively rapid, high-magnitude cooling of ∼120 to 200 ° C interpreted as erosional exhumation of upper crustal basement during the Cryogenian. These models imply widespread, synchronous cooling consistent with at least ∼3 to 5 km of unroofing during snowball Earth glaciations, but also demonstrate that plate tectonic drivers, with the potential to cause both exhumation and burial, may have significantly influenced the thermal history in regions that were undergoing deformation concomitant with glaciation. In the cratonic interior, however, glaciation remains the only plausible mechanism that satisfies the required timing, magnitude, and broad spatial pattern of continental erosion revealed by our thermochronological inversions. To obtain a full picture of the extent and synchroneity of such erosional exhumation, studies on stable cratonic crust below the Great Unconformity must be repeated on all continents. 

Abstract U-Pb geochronology by isotope dilution–thermal ionization mass spectrometry (ID-TIMS) has the potential to be the most precise and accurate of the deep time chronometers, especially when applied to high-U minerals such as zircon. Continued analytical improvements have made this technique capable of regularly achieving better than 0.1% precision and accuracy of dates from commonly occurring high-U minerals across a wide range of geological ages and settings. To help maximize the long-term utility of published results, we present and discuss some recommendations for reporting ID-TIMS U-Pb geochronological data and associated metadata in accordance with accepted principles of data management. Further, given that the accuracy of reported ages typically depends on the interpretation applied to a set of individual dates, we discuss strategies for data interpretation. We anticipate that this paper will serve as an instructive guide for geologists who are publishing ID-TIMS U-Pb data, for laboratories generating the data, the wider geoscience community who use such data, and also editors of journals who wish to be informed about community standards. Combined, our recommendations should increase the utility, veracity, versatility, and “half-life” of ID-TIMS U-Pb geochronological data.